Optimization of methanol yield and carbon dioxide utilization in methanol synthesis process
DOI:
https://doi.org/10.62051/hbcrht96Keywords:
methanol synthesis; methanol yield; CO2 utilization rate.Abstract
The method of CO2 hydrogenation to methanol can effectively reduce carbon emission and has wide application prospects in chemical industry and environment. Therefore, methanol synthesis is an important way to save energy, reduce emission and transform energy utilization. In this paper, the mathematical model of methanol synthesis reactor is established. Under the condition of controllable cooling temperature, the optimization is carried out with maximum methanol yield and CO2 utilization rate. The results show that the methanol yield can be increased by 6.57% and CO2 utilization rate can be increased to 39.1% by adjusting the cooling temperature control strategy. The comparative study found that the optimal cooling temperatures all show up and down variations, with local minima and maxima. In addition, an industrial application method of methanol yield maximization cooling strategy is proposed. When the stage cooling at different temperatures is adopted, the methanol yield could be increased by 5.38%.
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[1] Friedlingstein P, Sullivan M, Jones M W. Global carbon budget 2023. Earth System Science Data, 2023, 14(11): 4811-4900.
[2] Saeidi S, Saeidi N A S, Rahimpour M R. Hydrogenation of CO2 to value-added products-A review and potential future developments. Journal of CO2 Utilization, 2014, 5: 66-81.
[3] Modak A, Bhanja P, Dutta S. Catalytic reduction of CO2 into fuels and fine chemicals. Green Chem, 2020, 22(13): 4002-4033.
[4] Jahanmiri A, Eslamloueyan R. Optimal temperature profile in methanol synthesis reactor. Chemical Engineering Communications, 2002, 189(6): 713-741.
[5] Kordabadi H, Jahanmiri A. Optimization of methanol synthesis reactor using genetic algorithms. Chemical Engineering Journal, 2005, 108(3): 249-255.
[6] Lim H, Jun H J, Park M. Optimization of methanol synthesis reaction on Cu/ZnO/Al2O3/ZrO2 catalyst using genetic algorithm: Maximization of the synergetic effect by the optimal CO2 fraction. The Korean Journal of Chemical Engineering, 2010, 27(6): 1760-1767.
[7] Khademi M H, Rahimpour M R, Jahanmiri A. Start-up and dynamic analysis of a novelthermally coupled reactor for the simultaneous production of methanol and benzene. Ind Eng. Chem. Res., 2011, 50:12092-12102.
[8] Kjelstrup S, Johannessen E, Rosjorde A. Minimizing the entropy production of the methanol producing reaction in a methanol reactor. International Journal of Thermodynamics, 2000, 3(4): 147-153.
[9] Rafiee M. Modelling and optimization of methanol synthesis from hydrogen and CO2. Journal of Environmental Chemical Engineering. 2020, 8: 104314.
[10] Ergun S. Fluid flow through packed columns. Chemical Engineering Progress, 1952, 48: 89-94.
[11] Bussche K M V, Froment G F. A steady-state kinetic model for methanol synthesis and the water gas shift reaction on a commercial Cu/ZnO/Al2O3 catalyst. Journal of Catalysis, 1996, 161(1): 1-10.
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