Advancements in Research on Composite Bipolar Plates for Proton Exchange Membrane Fuel Cells
DOI:
https://doi.org/10.62051/dzp9m726Keywords:
Composite bipolar plate; PEMFC; synergy; dual percolation effect.Abstract
In proton exchange membrane fuel cells (PEMFC), the bipolar plate is a crucial component. Positioned between the anode and cathode, it supports the electrode reactions and provides pathways for gas flow. Made of conductive materials, it boasts excellent conductivity and mechanical stability, capable of withstanding the current generated by electrochemical reactions and resisting the corrosive and oxidative environments within the system. Thus, to ensure efficient energy conversion, the bipolar plate must exhibit good conductivity, mechanical strength, and corrosion resistance. This thesis systematically categorizes the selection of resins and graphite, based on a graphite-resin composite system, and compares the performance of various composite bipolar plates against the Department of Energy (DOE) standards. By examining the microstructure, the thesis explores the reasons behind these performance characteristics, aiming to determine the optimal graphite-resin ratio and modification methods.
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Kim M, Lim J W, Kim K H. Bipolar plates made of carbon fabric/phenolic composite reinforced with carbon black for PEMFC. Composite Structures. Vol. 96 (2013), p. 569-575.
Yin Q, Li A J, Sun K N, et al. Preparation of high-performance phenolic-formaldehyde resin/graphite bipolar plate conductive composite materials. modern chemical industry. (2007) No. S1, p. 220-223.
Yao K, Adams D, Hao A, et al. Highly conductive and strong graphite-phenolic resin composite for bipolar plate applications. Energy & fuels. Vol. 31 (2017) No. 12, p. 14320-14331.
Cui T, Li P, Liu Y, et al. Preparation of thermostable electroconductive composite plates from expanded graphite and polyimide. Materials Chemistry and Physics. Vol. 134 (2012) No. 2-3, p. 1160-1166.
Wang X, Wei S, Wu Y, et al. Achieving high electrochemical performance of PEMFCs with ultrathin and highly conductive graphite-resin composite bipolar plates. International Journal of Hydrogen Energy. Vol. 55 (2024), p. 654-664.
Hwang I U, Yu H N, Kim S S, et al. Bipolar plate made of carbon fiber epoxy composite for polymer electrolyte membrane fuel cells. Journal of power sources. Vol. 184 (2008) No. 1, p. 90-94.
Kim M, Lim J W. Surface modification of carbon fiber phenolic bipolar plate for the HT-PEMFC with nano-carbon black and carbon felts. Composite structures. Vol. 119 (2015), p. 630-637.
Kuan Y D, Ciou C W, Shen M Y, et al. Bipolar plate design and fabrication using graphite reinforced composite laminate for proton exchange membrane fuel cells. International Journal of Hydrogen Energy. Vol. 46 (2021) No. 31, p. 16801-16814.
Madheswaran D K, Thangavelu P. Reviewing carbon nanotube fillers for enhanced conductivity in proton exchange membrane fuel cell bipolar plates. Materials Letters. Vol. 358 (2024), p. 135838.
Ramírez-Herrera C A, Tellez-Cruz M M, Pérez-González J, et al. Enhanced mechanical properties and corrosion behavior of polypropylene/multi-walled carbon nanotubes/carbon nanofibers nanocomposites for application in bipolar plates of proton exchange membrane fuel cells. International Journal of Hydrogen Energy. Vol. 46 (2021) No. 51, p. 26110-26125.
Xiao M, Lu Y, Wang S J, et al. Poly (arylene disulfide)/graphite nanosheets composites as bipolar plates for polymer electrolyte membrane fuel cells. Journal of Power Sources. Vol. 160 (2006) No. 1, p. 165-174.
Liao S H, Hsiao M C, Yen C Y, et al. Novel functionalized carbon nanotubes as cross-links reinforced vinyl ester/nanocomposite bipolar plates for polymer electrolyte membrane fuel cells. Journal of Power Sources. Vol. 195 (2010) No. 23, p. 7808-7817.
Liao S H, Weng C C, Yen C Y, et al. Preparation and properties of functionalized multiwalled carbon nanotubes/polypropylene nanocomposite bipolar plates for polymer electrolyte membrane fuel cells. Journal of Power Sources. Vol. 195 (2010) No. 1, p. 263-270.
Kuan Y D, Ciou C W, Shen M Y, et al. Bipolar plate design and fabrication using graphite reinforced composite laminate for proton exchange membrane fuel cells. International Journal of Hydrogen Energy. Vol. 46 (2021) No. 31, p. 16801-16814.
Hwang I U, Yu H N, Kim S S, et al. Bipolar plate made of carbon fiber epoxy composite for polymer electrolyte membrane fuel cells. Journal of power sources. Vol. 184 (2008) No. 1, p. 90-94.
Kang K, Park S, Ju H. Effects of type of graphite conductive filler on the performance of a composite bipolar plate for fuel cells. Solid State Ionics. Vol. 262 (2014), p. 332-336.
de Oliveira M C L, Sayeg I J, Ett G, et al. Corrosion behavior of polyphenylene sulfide–carbon black–graphite composites for bipolar plates of polymer electrolyte membrane fuel cells. International journal of hydrogen energy. Vol. 39 (2014) No. 29, p. 16405-16418.
Chang F R. Preparation and performance study of expanded graphite/polyimide composite bipolar plate (Master's thesis, East China University of Science and Technology, 2015).
Wang J. Preparation and performance study of carbon microsphere-based bipolar plate composite materials (Master's thesis, Harbin Institute of Technology, 2017).
Gautam R K, Kar K K. Synergistic effects of carbon fillers of phenolic resin based composite bipolar plates on the performance of PEM fuel cell. Fuel Cells. Vol. 16 (2016) No. 2, p. 179-192.
Kakati B K, Ghosh A, Verma A. Efficient composite bipolar plate reinforced with carbon fiber and graphene for proton exchange membrane fuel cell. International journal of hydrogen energy. Vol. 38 (2013) No. 22, p. 9362-9369.
Jeong K I, Oh J, Song S A, et al. A review of composite bipolar plates in proton exchange membrane fuel cells: Electrical properties and gas permeability. Composite Structures. Vol. 262 (2021), p. 113617.
You M M. Preparation and performance study of fiber-reinforced resin/graphite composite bipolar plate (Master's thesis, Shandong University, 2011).
Darıcık F, Topcu A, Aydın K, et al. Carbon nanotube (CNT) modified carbon fiber/epoxy composite plates for the PEM fuel cell bipolar plate application. International Journal of Hydrogen Energy. Vol. 48 (2023) No. 3, p. 1090-1106.
Yin Q. Preparation and performance study of carbon nanotube-reinforced phenolic-formaldehyde resin/graphite composite bipolar plate (Master's thesis, Shandong University, 2008).
Dhakate S R, Sharma S, Chauhan N, et al. CNTs nanostructuring effect on the properties of graphite composite bipolar plate. International Journal of hydrogen energy. Vol. 35 (2010) No. 9, p. 4195-4200.
Witpathomwong S, Okhawilai M, Jubsilp C, et al. Highly filled graphite/graphene/carbon nanotube in polybenzoxazine composites for bipolar plate in PEMFC. International Journal of Hydrogen Energy. Vol. 45 (2020) No. 55, p. 30898-30910.
Lee J H, Jang Y K, Hong C E, et al. Effect of carbon fillers on properties of polymer composite bipolar plates of fuel cells. Journal of Power Sources. Vol. 193 (2009) No. 2, p. 523-529.
Hu B, Chang F L, Xiang L Y, et al. High performance polyvinylidene fluoride/graphite/multi-walled carbon nanotubes composite bipolar plate for PEMFC with segregated conductive networks. International Journal of Hydrogen Energy. Vol. 46 (2021) No. 50, p. 25666-25676.
Li W, Jing S, Wang S, et al. Experimental investigation of expanded graphite/phenolic resin composite bipolar plate. International Journal of Hydrogen Energy. Vol. 41 (2016) No. 36, p. 16240-16246.
Kim M, Lim J W, Kim K H. Ultra high speed curing bipolar plates made of carbon fabric/phenolic composite using acid catalyst for proton exchange membrane fuel cell. Composite Structures. Vol. 108 (2014), p. 1-8.
Kakati B K, Deka D. Differences in physico-mechanical behaviors of resol (e) and novolac type phenolic resin based composite bipolar plate for proton exchange membrane (PEM) fuel cell. Electrochimica Acta. Vol. 52 (2007) No. 25, p. 7330-7336.
Du C, Ming P, Hou M, et al. Preparation and properties of thin epoxy/compressed expanded graphite composite bipolar plates for proton exchange membrane fuel cells. Journal of Power Sources. Vol. 195 (2010) No. 3, p. 794-800.
Xia L, Li A, Wang W, et al. Effects of resin content and preparing conditions on the properties of polyphenylene sulfide resin/graphite composite for bipolar plate. Journal of power sources. Vol. 178 (2008) No. 1, p. 363-367.
Liao S H, Yen C Y, Weng C C, et al. Preparation and properties of carbon nanotube/polypropylene nanocomposite bipolar plates for polymer electrolyte membrane fuel cells. Journal of Power Sources. Vol. 185 (2008) No. 2, p. 1225-1232.
Lim J W, Kim M, Yu Y H. Development of carbon/PEEK composite bipolar plates with nano-conductive particles for High-Temperature PEM fuel cells (HT-PEMFCs). Composite structures. Vol. 118 (2014), p. 519-527.
Zeng H D. Preparation and performance study of graphite/polyimide-PEEK resin composite bipolar plate for PEMFC (Master's thesis, Central South University, 2022).
Lee D. Carbon composite bipolar plate for high-temperature proton exchange membrane fuel cells (HT-PEMFCs). Journal of Power Sources. Vol. 327 (2016), p. 119-126.
Chen J, Fan R, Peng Y, et al. Tuning the performance of composite bipolar plate for proton exchange membrane fuel cell by modulating resin network structure. Journal of Power Sources. Vol. 582 (2023), p. 233566.
Lee H E, Chung Y S, Kim S S. Feasibility study on carbon-felt-reinforced thermoplastic composite materials for PEMFC bipolar plates. Composite Structures. Vol. 180 (2017), p. 378-385.
Soares da Silva J P, Soares B G, Silva A A, et al. Double percolation of melt-mixed PS/PBAT blends loaded with carbon nanotube: Effect of molding temperature and the non-covalent functionalization of the filler by ionic liquid. Frontiers in Materials. Vol. 6 (2019), p. 191.
Lee H E, Han S H, Song S A, et al. Novel fabrication process for carbon fiber composite bipolar plates using sol gel and the double percolation effect for PEMFC. Composite Structures. Vol. 134 (2015), p. 44-51.
Ghosh P, Ganguly S, Kargupta K. Phosphosilicate nano-network (PPSN)-Polybenzimidazole (PBI) composite electrolyte membrane for enhanced proton conductivity, durability and power generation of HT-PEMFC. International Journal of Hydrogen Energy. Vol. 47 (2022) No. 75, p. 32287-32302.
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