A Unified Research on Advanced Biodegradable Copolymers Based on Their Biodegradable Properties
DOI:
https://doi.org/10.62051/6rzztt85Keywords:
Biodegradable Materials; PLA; PHA; PBS; Carbon Dioxide Copolymers.Abstract
Recently, biodegradable materials can effectively reduce the environmental hazards. However, they still have limitations in terms of degradation rate and stability. This paper systematically reviews the progress of various biodegradable materials, such as polylactic acid, polyhydroxy-fatty acid ester, polybutylene succinate, and carbon dioxide copolymer. This study found that the degradation rate of polylactic acid can be enhanced through composite methods involving biomaterials. Polyhydroxyl fatty acid esters were synthesized using copolymer preparation, solution pouring, and hot pressing techniques in order to improve their degradation rate. Furthermore, the degradation rate of polybutanediol succinate was improved through composites with biomaterials as well as organic and inorganic materials. Lastly, the degradation rate of carbon dioxide copolymers can be enhanced by utilizing copolymers formed from carbon dioxide monomers along with other polymers or monomers in composite materials. Polylactic acid prepared by the composite method of biological materials can improve the utilization rate of biological resources. The mass preparation of polyhydroxy-fatty acid esters in industry can be enhanced by solution pouring and hot pressing. The composite of polybutanediol succinate and biomaterials improved the mechanical properties. The preparation of carbon dioxide copolymers can improve the utilization of carbon dioxide and reduce greenhouse gases. Most importantly, this research can effectively enhance the degradation performance of biodegradable materials then reducing their impact on the environment.
Downloads
References
[1] Zhao X, Liu J, Li J, et al. Strategies and techniques for improving heat resistance and mechanical performances of poly (lactic acid) (PLA) biodegradable materials [J]. International Journal of Biological Macromolecules, 2022, 218: 115-134.
[2] Merino D, Zych A, Athanassiou A. Biodegradable and biobased mulch films: highly stretchable PLA composites with different industrial vegetable waste [J]. ACS applied materials & interfaces, 2022, 14 (41): 46920-46931.
[3] Sadeghi A, Razavi S M A, Shahrampour D. Fabrication and characterization of biodegradable active films with modified morphology based on polycaprolactone-polylactic acid-green tea extract [J]. International Journal of Biological Macromolecules, 2022, 205: 341-356.
[4] Wang L, Gao Y, Xiong J, et al. Biodegradable and high-performance multiscale structured nanofiber membrane as mask filter media via poly (lactic acid) electrospinning [J]. Journal of Colloid and Interface Science, 2022, 606: 961-970.
[5] Zou D, Zheng X, Ye Y, et al. Effect of different amounts of bamboo charcoal on properties of biodegradable bamboo charcoal/polylactic acid composites [J]. International Journal of Biological Macromolecules, 2022, 216: 456-464.
[6] Murillo-Morales G, Sethupathy S, Zhang M, et al. Characterization and 3D printing of a biodegradable polylactic acid/thermoplastic polyurethane blend with laccase-modified lignin as a nucleating agent [J]. International Journal of Biological Macromolecules, 2023, 236: 123881.
[7] Miu D M, Eremia M C, Moscovici M. Polyhydroxyalkanoates (PHAs) as biomaterials in tissue engineering: production, isolation, characterization [J]. Materials, 2022, 15 (4): 1410.
[8] Hyodo N, Gan H, Ilangovan M, et al. Coastal and deep-sea biodegradation of polyhydroxyalkanoate microbeads [J]. Scientific Reports, 2024, 14 (1): 10302.
[9] Injorhor P, Trongsatitkul T, Wittayakun J, et al. Biodegradable polylactic acid-polyhydroxyalkanoate-based nanocomposites with bio-hydroxyapatite: Preparation and characterization [J]. Polymers, 2023, 15 (5): 1261.
[10] Othman N A F, Selambakkannu S, Seko N. Biodegradable dual-layer polyhydroxyalkanoate (pha)/polycaprolactone (pcl) mulch film for agriculture: Preparation and characterization [J]. Energy Nexus, 2022, 8: 100137.
[11] Wongphan P, Nampanya P, Chakpha W, et al. Lesser galangal (Alpinia officinarum Hance) essential oil incorporated biodegradable PLA/PBS films as shelf-life extension packaging of cooked rice [J]. Food Packaging and Shelf Life, 2023, 37: 101077.
[12] Penas M I, Criado-Gonzalez M, de Ilarduya A M, et al. Tunable enzymatic biodegradation of poly (butylene succinate): biobased coatings and self-degradable films [J]. Polymer Degradation and Stability, 2023, 211: 110341.
[13] Ding Y, Wang J, Luo C, et al. Modification of poly (butylene succinate) with biodegradable glycolic acid: Significantly improved hydrolysis rate retaining high toughness property [J]. Journal of Applied Polymer Science, 2022, 139 (19): 52106.
[14] Rova L, Kurita H, Kudo S, et al. Variation of the tensile properties of basalt-fiber-reinforced polybutylene succinate matrix composites during microbial degradation [J]. Polymers, 2023, 15 (7): 1796.
[15] Shin N, Kim S H, Oh J, et al. Reproducible Polybutylene Succinate (PBS)-Degrading Artificial Consortia by Introducing the Least Type of PBS-Degrading Strains [J]. Polymers, 2024, 16 (5): 651.
[16] Wang W J, Ye S X, Liang J X, et al. Architecting branch structure in terpolymer of CO2, propylene oxide and phthalic anhydride: an enhancement in thermal and mechanical performances [J]. Chinese Journal of Polymer Science, 2022, 40 (5): 462-468.
[17] Wang W Z, Zhao C, Li L L, et al. Preparation of carbon dioxide, propylene oxide, and norbornene dianhydride terpolymers catalyzed via dinuclear cobalt complexes: Effective improvement of thermal, mechanical, and degradation properties [J]. Polymer, 2022, 256: 125188.
[18] Wang Z, Zheng W, Yue S, et al. Random Terpolymer of Carbon Dioxide, Butadiene and Epoxides: Synthesis, Functionalization and Degradability [J]. Chinese Journal of Chemistry, 2024.
[19] Tang S, Suo H, Qu R, et al. Copolymerization of Carbon Dioxide with 1, 2-Butylene Oxide and Terpolymerization with Various Epoxides for Tailorable Properties [J]. Polymers, 2023, 15 (3): 748.
[20] Chen K, Zhu Z, Bai T, et al. A Topology‐Defined Polyester Elastomer from CO2 and 1, 3‐Butadiene: A One‐Pot‐One‐Step “Scrambling Polymerizations” Strategy [J]. Angewandte Chemie International Edition, 2022, 61 (46): e202213028.
Downloads
Published
Conference Proceedings Volume
Section
License
Copyright (c) 2024 Transactions on Environment, Energy and Earth Sciences

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.