Research and Development of Silicon-Based Anode Materials for Lithium Ion Batteries
DOI:
https://doi.org/10.62051/gw73p671Keywords:
Silicon-based anodes, Lithium-ion batteries, Structural stability.Abstract
Silicon, known for its high capacity, has become a key material in developing anodes for lithium-ion batteries (LIBs). However, the substantial increase in volume that silicon-based anodes undergo during the process of charging and discharging presents a significant obstacle. This expansion can lead to structural disintegration and loss of electrical conductivity. It also initiates undesirable parasitic reactions, all of which significantly reduce the cycle life of the battery. Consequently, these issues hinder the wider adoption of silicon in the commercial LIB sector. This comprehensive review synthesizes key advancements in silicon-based anode research, highlighting the latest trends and innovations. This investigation examines the intricate engineering of silicon lattices and the development of silicon-based composite materials, illuminating the advancement in the field of silicon anode technologies, encompassing hybrid materials like silicon integrated with graphite and those amalgamated with various metals. Additionally, it scrutinizes the lithium storage characteristics and the mechanisms at play in silicon/graphene and other silicon composites. The review concludes with a forward-looking exploration of the future trajectory of silicon-based materials, considering their potential for growth and integration within the field.
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[1] Feng, K., Li, M., Liu, W., et al. Silicon-based anodes for lithium-ion batteries: from fundamentals to practical applications, Small 14 (2018) 1702737.
[2] Gao, P., Li, J., Zhao, Y., et al. Formation of Si hollow structures as promising anode materials through reduction of silica in AlCl3–NaCl molten salt, ACS Nano 12 (2018) 11481-11490.
[3] Zhu, R., Li, J., Zhou, H., et al. Double-shelled hollow carbon nanospheres as enclosed electrochemical reactors to enhance the lithium storage performance of silicon nanodots, J. Mater. Chem. An 8 (2020) 12502-12517.
[4] Park, M.-H., Kim, J., Cho, J., et al. Silicon nanotube battery anodes, Nano Lett. 9 (2009) 3844-3847.
[5] Szczech, J.R., Song, J. Nanostructured silicon for high capacity lithium battery anodes, Energy Environ. Sci. 4 (2011) 56-72.
[6] Hatchard, T.D., Dahn, J.R. Study of the electrochemical performance of sputtered Si1−xSnx films, J. Electrochem. Soc. 151 (2004) A1628.
[7] Song, T., Hu, L., Paik, U. One-dimensional silicon nanostructures for Li ion batteries, J. Phys. Chem. Lett. 5 (2014) 720-731.
[8] Hertzberg, B., Alexeev, A., Yushin, G. Deformations in Si−Li anodes upon electrochemical alloying in nano-confined space, J. Am. Chem. Soc. 132 (2010) 8548-8549.
[9] Wu, H., Chan, G., Choi, J.W., et al. Stable cycling of double-walled silicon nanotube battery anodes through solid–electrolyte interphase control, Nat. Nanotechnol. 7 (2012) 310-315.
[10] Karki, K., Kim, S., Lee, H., et al. Hoop-strong nanotubes for battery electrodes, ACS Nano 7 (2013) 8295-8302.
[11] Li, J., Zhang, Y., Li, Y., et al. Review on comprehending and enhancing the initial Coulombic efficiency of anode materials in lithium-ion/sodium-ion batteries, Nano Energy 77 (2020) 105143.
[12] Kubota, K., Komaba, S., Nakayama, T., et al. Towards K-ion and Na-ion batteries as “beyond Li-ion”, Chem. Rec. 18 (2018) 459-479.
[13] Kim, T., Lee, H., Ahn, S., et al. Lithium-ion batteries: outlook on present, future, and hybridized technologies, J. Mater. Chem. A (2019) n. pag.
[14] Choudhury, S., Archer, L.A., Zavadil, K.R., et al. Hybrid hairy nanoparticle electrolytes stabilizing lithium metal batteries, Chem. Mater. 28 (2016) 2147-2157.
[15] Holzapfel, M., Buqa, H., Krumeich, F., et al. A new type of nano-sized silicon/carbon composite electrode for reversible lithium insertion, Chem. Commun. (2005) 1566-1568.
[16] Datta, M.K., Kumta, P.N. Silicon and carbon based composite anodes for lithium ion batteries, J. Power Sources 158 (2006) 557-563.
[17] Lee, J.-H., Lee, D.J., Choi, D., et al. Spherical silicon/graphite/carbon composites as anode material for lithium-ion batteries, J. Power Sources 176 (2008) 353-358.
[18] Polat, D.B., Keles, O., Amine, K. Well-aligned, ordered, nanocolumnar, Cu–Si thin film as anode material for lithium-ion batteries, J. Power Sources 270 (2014) 238-247.
[19] Yu, R., Liu, Y., Zhang, J., et al. Constructing Sub 10 nm Scale Interfused TiO2/SiOx Bicontinuous Hybrid with Mutual-Stabilizing Effect for Lithium Storage, ACS Nano 17 (2023) 2568-2579.
[20] Luo, J., Fang, C., Li, J., et al. Crumpled graphene-encapsulated Si nanoparticles for lithium ion battery anodes, J. Phys. Chem. Lett. 3 (2012) 1824-1829.
[21] Cui, Y., Wang, L., Zhao, X., et al. A Hybrid Assembly of MXene with NH2− Si Nanoparticles Boosting Lithium Storage Performance, Chem.–Asian J. 15 (2020) 1376-1383.
[22] Abdollahifar, M., Ahn, D., Kim, H., et al. Enabling Long-Cycling Life of Si-on-Graphite Composite Anodes via Fabrication of a Multifunctional Polymeric Artificial Solid–Electrolyte Interphase Protective Layer, ACS Appl. Mater. Interfaces 14 (2022) 38824-38834.
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