Graphene Composite Materials for Removal of Heavy Metals from Water: Progress and Prospects
DOI:
https://doi.org/10.62051/ijnres.v4n2.07Keywords:
Graphene, Composite materials, Water treatment, Heavy metals.Abstract
With the acceleration of the global industrialization process, heavy metal pollution has become increasingly serious. Heavy metal elements pose a grave threat to the ecological environment and human health owing to their high virulence, strong persistence, and bioaccumulation. Therefore, developing efficient and environmentally friendly water treatment technologies to remove heavy metal (HM) in water has emerged as current focus of environmental science research. Graphene has shown significant application potential in water treatment owing to its unique physical and chemical properties. In particular, graphene composites can be further improved in water treatment by combining graphene with other materials. This paper systematically combs and analyzes relevant literature in recent years and summarizes the research progress of graphene composites (GCs) in removing HMs such as lead, mercury, cadmium, chromium and arsenic from water. The application status, mechanism of action, and performance evaluation of GCs in removing HMs in water treatment are discussed in detail. Finally, the challenges and future development directions are analyzed. Valuable reference and guidance for the further development of GCs in the field of water treatment are provided.
References
[1] Pan, H. Preparation of Graphene Oxide Based Materials and Study on Their Removal Performance of Cr(VI) and Cd(II) in Water. Master, Anhui Jianzhu University, 2022.
[2] Yari, M.; Rajabi, M.; Moradi, O.; et al. Kinetics of the adsorption of Pb(II) ions from aqueous solutions by graphene oxide and thiol functionalized graphene oxide. Journal of Molecular Liquids 2015, 209, 50-57.
[3] Zhang, Y.; Yan, L.; Xu, W.; et al. Adsorption of Pb(II) and Hg(II) from aqueous solution using magnetic CoFe2O4-reduced graphene oxide. Journal of Molecular Liquids 2014, 191, 177-182.
[4] Li, F.; Wang, X.; Yuan, T.; et al. A lignosulfonate-modified graphene hydrogel with ultrahigh adsorption capacity for Pb(ii) removal. Journal of Materials Chemistry A 2016, 4 (30), 11888-11896.
[5] Hao, L.; Song, H.; Zhang, L.; et al. SiO2/graphene composite for highly selective adsorption of Pb(II) ion. J Colloid Interface Sci 2012, 369 (1), 381-387.
[6] Ma, Y. X.; Kou, Y. L.; Xing, D.; et al. Synthesis of magnetic graphene oxide grafted polymaleicamide dendrimer nanohybrids for adsorption of Pb(II) in aqueous solution. J Hazard Mater 2017, 340, 407-416.
[7] Z., L. Study on the rapid adsorption and removal of Cd (II) in water by tea saponin modified reduced graphene oxide [D]. Hunan University. 2018.
[8] G., W.; Y., G.; D., Q.; et al. Methodological study on simultaneous determination of lead and cadmium content in water: based on reduced graphene oxide electro deposited mercury film modified glassy carbon electrode. Environmental and Occupational Medicine 2020, 37 (05), 514-519.
[9] Deng, J.; Zhang, X.; Zeng, G.; et al. Simultaneous removal of Cd(II) and ionic dyes from aqueous solution using magnetic graphene oxide nanocomposite as an adsorbent. Chemical Engineering Journal 2013, 226, 189-200.
[10] Bao, S.; Yang, W.; Wang, Y.; et al. One-pot synthesis of magnetic graphene oxide composites as an efficient and recoverable adsorbent for Cd(II) and Pb(II) removal from aqueous solution. J Hazard Mater 2020, 381, 120914.
[11] T., Z.; C., X. The removal performance and mechanism of cadmium and malachite green in printing and dyeing wastewater using novel graphene oxide bio nanomaterials. Journal of Environmental Science 2021, 41 (06), 2138-2146.
[12] Tang, J.; Huang, Y.; Gong, Y.; et al. Preparation of a novel graphene oxide/Fe-Mn composite and its application for aqueous Hg(II) removal. J Hazard Mater 2016, 316, 151-158.
[13] R., J. Preparation of graphene oxide/carrageenan composite hydrogel and its adsorption properties for dyes and heavy metals in water. Northeastern University, 2019.
[14] Qu, Z.; Fang, L.; Chen, D.; et al. Effective and regenerable Ag/graphene adsorbent for Hg(II) removal from aqueous solution. Fuel 2017, 203, 128-134.
[15] Li, R.; Liu, L.; Yang, F. Preparation of polyaniline/reduced graphene oxide nanocomposite and its application in adsorption of aqueous Hg(II). Chemical Engineering Journal 2013, 229, 460-468.
[16] Aghdam, K.; Panahi, H. A.; Alaei, E. Preparation of functionalized graphene oxide and its application as a nanoadsorbent for Hg(2+) removal from aqueous solution. Environ Monit Assess 2016, 188 (4), 223.
[17] Awad, F. S.; AbouZied, K. M.; Bakry, A. M.; et al. Polyacrylonitrile modified partially reduced graphene oxide composites for the extraction of Hg(II) ions from polluted water. Journal of Materials Science 2021, 56 (13), 7982-7999.
[18] Bandara, P. C.; Pena-Bahamonde, J.; Rodrigues, D. F. Redox mechanisms of conversion of Cr(VI) to Cr(III) by graphene oxide-polymer composite. Sci Rep 2020, 10 (1), 9237.
[19] Chen, Z.; Li, Y.; Guo, M.; et al. One-pot synthesis of Mn-doped TiO2 grown on graphene and the mechanism for removal of Cr(VI) and Cr(III). J Hazard Mater 2016, 310, 188-198.
[20] Li, Y.; Cui, W.; Liu, L.; et al. Removal of Cr(VI) by 3D TiO2 -graphene hydrogel via adsorption enriched with photocatalytic reduction. Applied Catalysis B: Environmental 2016, 199, 412-423.
[21] Dinda, D.; Gupta, A.; Saha, S. K.; et al. Removal of toxic Cr(vi) by UV-active functionalized graphene oxide for water purification. Journal of Materials Chemistry A 2013, 1 (37). 11221–11228
[22] Ma, H.; Zhang, Y.; Hu, Q.; et al. Chemical reduction and removal of Cr(vi) from acidic aqueous solution by ethylenediamine-reduced graphene oxide. Journal of Materials Chemistry 2012, 22 (13). 5914–5916
[23] Zhang, L.; Luo, H.; Liu, P.; et al. A novel modified graphene oxide/chitosan composite used as an adsorbent for Cr(VI) in aqueous solutions. Int J Biol Macromol 2016, 87, 586-596.
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