The Mineral Composition and Hydration Behavior of Cement Clinker Under Different KH Values
DOI:
https://doi.org/10.62051/ijmsts.v3n3.04Keywords:
Low-Heat Portland cement, Hydration heat, Clinker mineralogyAbstract
This study investigates the effects of varying lime saturation factors (KH = 0.85, 0.87, 0.90, 0.92) on the mineral composition and hydration behavior of low-heat Portland cement (LHC) clinker, providing theoretical guidance for its industrial production. X-ray diffraction (XRD), scanning electron microscopy (SEM), and hydration heat tests were employed to analyze the phase composition, microstructure, and hydration characteristics of the clinker. The results indicate that as KH increases, the C₃S content rises while the C₂S content decreases, leading to a significant increase in hydration heat peak values and cumulative heat release, as well as enhanced compressive strength. When KH = 0.90, the 7-day hydration heat reaches 276.8 J/g, and the 28-day compressive strength is 43.5 MPa, meeting the GB/T 200-2017 standard for low-heat cement (≤260 J/g) while exhibiting excellent mechanical performance.
References
[1] Jian S, Gao W, Lv Y, et al. Potential utilization of copper tailings in the preparation of low heat cement clinker [J]. Construction and Building Materials, 2020, 252.
[2] Ma Z, Yao Y, Liu Z, et al. Effect of calcination and cooling conditions on mineral compositions and properties of high-magnesia and low-heat Portland cement clinker [J]. Construction and Building Materials, 2020, 260.
[3] Xie J, Wu Z, Zhang X, et al. Trends and developments in low-heat portland cement and concrete: A review [J]. Construction and Building Materials, 2023, 392.
[4] Scherb S, Maier M, Köberl M, et al. Reaction kinetics during early hydration of calcined phyllosilicates in model cement systems [J]. Cement and Concrete Research, 2024, 175.
[5] Shu X, Jiang Y, Zhao Y, et al. Superimposed hydration exothermic model of cement slurry considering different reaction rates of various active substances [J]. Construction and Building Materials, 2023, 372.
[6] Yan Y, Scrivener K L, Yu C, et al. Effect of a novel starch-based temperature rise inhibitor on cement hydration and microstructure development: The second peak study [J]. Cement and Concrete Research, 2021, 141.
[7] Zhao Y, Chen P, Wang S, et al. Utilization of Bayer Red Mud Derived from Bauxite for Belite-Ferroaluminate Cement Production [J]. Journal of Renewable Materials, 2020, 8(11): 1531-41.
[8] Wang L, Dong Y, Zhou S H, et al. Energy saving benefit, mechanical performance, volume stabilities, hydration properties and products of low heat cement-based materials [J]. Energy and Buildings, 2018, 170: 157-69.
[9] Jia F, Yao Y, Wang J. Influence and Mechanism Research of Hydration Heat Inhibitor on Low-Heat Portland Cement [J]. Frontiers in Materials, 2021, 8.
[10] Yanagisawa K, Hu X, Onda A, et al. Hydration of β-dicalcium silicate at high temperatures under hydrothermal conditions [J]. Cement and Concrete Research, 2006, 36(5): 810-6.
[11] Zheng J, Wei S, Wang Q, et al. Kinetics of alite formation and ye’elimite decomposition in alite-ye’elimite cement clinker [J]. Chemical Papers, 2021, 75(11): 5983-93.
[12] Bohac M, Zezulova A, Krejci Kotlanova M, et al. Early hydration of C(4)AF with silica fume and its role on katoite composition [J]. J Microsc, 2024, 294(2): 168-76.
[13] Huang X, Hu S, Wang F, et al. The effect of supplementary cementitious materials on the permeability of chloride in steam cured high-ferrite Portland cement concrete [J]. Construction and Building Materials, 2019, 197: 99-106.
[14] Huo B, Zhang Y. Effects of dicalcium ferrite on hydration and microstructure of cementitious material [J]. Construction And Building Materials, 2024, 411.
[15] Maddalena R, Roberts J J, Hamilton A. Can Portland cement be replaced by low-carbon alternative materials? A study on the thermal properties and carbon emissions of innovative cements [J]. Journal of Cleaner Production, 2018, 186: 933-42.
[16] Wang Q, Yan P, Han S. The influence of steel slag on the hydration of cement during the hydration process of complex binder [J]. Science China-Technological Sciences, 2011, 54(2): 388-94.
[17] Xue J, Liu S, Ma X, et al. Effect of different gypsum dosage on the chloride binding properties of C4AF hydrated paste [J]. Construction and Building Materials, 2022, 315.
[18] Zhang K, Wang C, Huang X. Insight into discrepancies in hydration reactivity of ferrite phase in Portland cement clinker and synthetics [J]. Construction and Building Materials, 2024, 412.
[19] Wang K, Liu Y, Dou Z, et al. A Novel Method of Extracting Iron from High-Iron Red Mud and Preparing Low-Carbon Cement Clinker from Tailings [J]. Jom, 2022, 74(7): 2750-9.
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