Study of Shaped Shapes of Cellulose Acetate Films Based on Mie Scattering
DOI:
https://doi.org/10.62051/ijmsts.v3n1.05Keywords:
Cellulose acetate, Mie scattering, Heteromorphic shape, Scattering efficiency, Backscattering efficiency factorAbstract
The emerging cellulose acetate film is also a composite material with excellent cooling properties due to its excellent flexibility and good film-forming properties, and nowadays it has become a key material used for radiation cooling. Since the cross-section of the columnar skeleton of cellulose acetate film is irregular and heterogeneous, which is not the traditional circular shape, at present, domestic and foreign research mainly analyses the circular shape, and does not explore the influence of the heterogeneous shape on the scattering effect of cellulose acetate film in depth. Therefore, in this paper, through the Mie scattering formula, the complex refractive index of cellulose acetate film in actual measurement is substituted into the formula for the simulation of scattering efficiency, extinction efficiency, absorption efficiency and backward scattering efficiency factor of the particles, and on the basis of this, different size parameters of the particles are simulated to obtain the relationship between the scattering direction of the particles and the size parameters. After that, the heteromorphic shape was modelled and simulated based on the Fourier formula in polar coordinates, which was substituted into the simulation software for comparing the light scattering cross section of the heteromorphic shape with that of the traditional circular shape, and then the heteromorphic shape was adjusted and optimized on the basis of the same cellulose acetate film. It is found that the heteromorphic shape has a larger surface area than a circle, and its special shape can form an asymmetric radiation route, which can scatter the light emitted from the side better, thus providing a feasible graphical solution for the preparation of cellulose acetate radiation-cooled films.
References
[1] Raman, A. P., Anoma, M. A., Zhu, L., Rephaeli, E. & Fan, S. Passive radiative cooling below ambient air temperature under direct sunlight. Nature 515, 540 -- 544 (2014)
[2] Lv Song; Ji Yishuang; Ji Yitong; Qian Zuoqin; Ren Juwen; Zhang Bolong; Lai Yin; Yang Jiahao; Chang Zhihao.Experimental and numerical comparative investigation on 24h radiative cooling performance of a simple organic composite film. Journal | [J] Energy. Volume 261, Issue PA. 2022.
[3] W. Lu et al., Porous membranes in secondary battery technologies. Chemical Society Reviews 46, 2199-2236 (2017).
[4] Yuan Shuaixia. Preparation and application of natural cellulose based daytime passive radiation refrigeration materials.
[5] Chen Xi. Cellulose-based porous polymer film with auto-deposited TiO2 as spectrally selective materials for passive daytime radiative cooling. Optical Materials Volume 120, October 2021, 111431.
[6] Jia Jianru. Study on modification and properties of cellulose acetate nanofiber membrane.
[7] Feng M, Feng S, Liu C, et al. Integrated passive cooling fabrics with bioinspired perspiration-wicking for outdoor personal thermal management [J]. Composites Part B: Engineering, 2023, 264: 110875.
[8] Zhang K, Mo C, Tang X, et al. Hierarchically Porous Cellulose-Based Radiative Cooler for Zero-Energy Food Preservation [J]. ACS Sustainable Chemistry & Engineering, 2023, 11(20):7745-7754.
[9] Zheng Y, Zhu Y, Yu Z, et al. Passive thermal regulation with 3D printed phase change material/cellulose nanofibrils composites [J]. Composites Part B: Engineering, 2022, 247: 110332.
[10] Li T, Zhai Y, He S, et al. A radiative cooling structural material [J]. Science, 2019, 364(6442): 760-763.
[11] ZHU Jia, WANG Minghuai "Protecting ice from melting under sunlight via radiative cooling".
[12] Chen Xi Study on preparation and cooling performance of passive daytime radiative cooling film.
[13] Wei Wei, Yong Zhu, Qiu LiAn Al₂O₃-cellulose acetate-coated textile for human body cooling.
[14] Yuxin Zhang, Dingsheng Wu, Shiqin Liao A multi-mode cellulose acetate/MXene Janus film with structure enhanced self-reflection, selective emission and absorption for cooling and heating.
[15] Chen Si, Yang Xujie Design and properties of radiative cooling materials based on spectral selectivity.
[16] C. Y. Jim, W. Y. Chan, et al."Solar Reflectance and Thermal Emissivity of Cool Roofs".
[17] W. S. Cai, G. Li, et al. "Passive radiative cooling below ambient air temperature under direct sunlight".
[18] Tong Wang, Yi Wu, Lan Shi, et, al. A structural polymer for highly efficient all-day passive radiative cooling. Nature Communications, 2021, 12 (1) : 365.
[19] Ren Zeyu. [19] Preparation of cellulose nanofiber composite aerogel and its daytime radiation refrigeration performance.
[20] Chen Xi. Cellulose-based porous polymer film with auto-deposited TiO2 as spectrally selective materials for passive daytime radiative cooling. Optical Materials Volume 120, October 2021, 111431.
[21] Benoit Rousseau, Domingos De Sousa Meneses, Patrick Echegut, Jean-Francois Thover. Textural parameters influencing the system radiative properties of a semitransparent porous media. International Journal of Thermal Sciences 50 (2011) 178e186.
[22] Juan C. Araujo, Eddie Wadbro, Shape optimization for the strong directional scattering of dielectric nanorods.
[23] Yang Guoguang, Song Feijun. Advanced Physical Optics [M]. University of Science and Technology of China Press, 2008.
[24] HOU Honglu, Liu Kai, Zhao Qunying. Numerical simulation of light scattering properties of soot aerosols [J]. Journal of Xi 'an Technological University, 2016, 36(09): 719-725.
[25] Gao Tian-Le. Correction and fusion of aerosol active and passive detection for oblique visibility [D]. Xi 'an University of Technology, 2020. (in Chinese)
[26] Han Yingbo, Xu DeZeng, CAI Yuefen, et al. [26] Discussion on modification method of polyester fiber [J]. Polyester Industry, 2003, 16 (2) : 11-14. HAN Yingbo, XU Dezeng, CAI Yuefen, et al. Discussion on modified methods of polyester [J]. Polyester Industry, 2003, 16(2): 11-14.
[27] Liu Lu. Optimal design of nonwoven air filtration materials: Influence of fiber morphology [D]. Tianjin: Tianjin Polytechnic University, 202:1-2. (in Chinese) LIU Lu. Optimal Design of Nonwoven Air Filter Materials: The Influence of Fiber Morphology [D]. Tianjin: Tianjin Polytechnic University, 2021: 1-2.
[28] Wang Huiyun. [28] Preparation and properties of polyacrylonitrile fiber with triangular polyspace [D]. Suzhou: Soochow University, 202:2. WANG Huiyun. Preparation of PAN Triangular Hollow Porous Fiber and Its Performance [D]. Soochow University, 2021: 2.
Downloads
Published
Issue
Section
License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.







