Synthesis and Optical Properties of Bismuth-based Perovskite Materials
DOI:
https://doi.org/10.62051/ijmsts.v2n3.02Keywords:
Bismuth-based perovskite material, Optical properties, Carrier, PhotocatalysisAbstract
Bismuth-based perovskite has become the best candidate material for non-lead perovskite because of its low toxicity and good moisture stability. The structural diversity of bismuth halide perovskites gives them many photoelectric properties, such as nonlinear optical properties, photochromic effects and photoelectric effects. However, bismuth halide perovskite materials with different stoichiometric ratios have different light absorption properties and carrier transport processes. In order to search for high stability and excellent optical properties of bismuth halide perovskite materials, this paper synthesized Rb3BiBr6 materials by using rubidium bromide and bismuth bromide as precursors, and further studied the morphology and optical properties of the materials by scanning electron microscopy, UV-VIS absorption spectroscopy, ultraviolet photoelectron spectroscopy and nanosecond transient absorption spectroscopy. The results show that the material has a wide light absorption range and a long carrier transfer process, indicating that the bismuth-based perovskite material has great application value in the field of photocatalysis and photodetector.
References
[1] Wang, J., Wang, J., Li, N., et al. (2020). Direct Z-scheme 0D/2D heterojunction of CsPbBr3 quantum dots/Bi2WO6 nanosheets for efficient photocatalytic CO2 reduction. ACS Applied Materials & Interfaces, 12(28), 31477-31485.
[2] Bi, W., Leblanc, N., Mercier, N., et al. (2009). Thermally induced Bi (III) lone pair stereoactivity: ferroelectric phase transition and semiconducting properties of (MV) BiBr5 (MV= methylviologen). Chemistry of materials, 21(18), 4099-4101.
[3] Park, B. W., Philippe, B., Zhang, X., et al. (2015). Bismuth Based Hybrid Perovskites A3Bi2I9 (A: Methylammonium or Cesium) for Solar Cell Application. Advanced Materials (Deerfield Beach, Fla.), 27(43), 6806-6813.
[4] Shi, M., Li, G., Tian, W., et al. (2020). Understanding the effect of crystalline structural transformation for lead‐free inorganic halide perovskites. Advanced Materials, 32(31), 2002137.
[5] Lehner, A. J., Fabini, D. H., Evans, H. A., et al. (2015). Crystal and electronic structures of complex bismuth iodides A3Bi2I9 (A=K, Rb, Cs) related to perovskite: aiding the rational design of photovoltaics. Chemistry of materials, 27(20), 7137-7148.
[6] Tran, M. N., Cleveland, I. J., & Aydil, E. S. (2020). Resolving the discrepancies in the reported optical absorption of low-dimensional non-toxic perovskites, Cs3Bi2Br9 and Cs3BiBr6. Journal of Materials Chemistry C, 8(30), 10456-10463.
[7] Zhang, J., Yang, Y., Deng, H., et al. (2017). High quantum yield blue emission from lead-free inorganic antimony halide perovskite colloidal quantum dots. ACS nano, 11(9), 9294-9302.
[8] Yang, H., Cai, T., Liu, E., et al. (2020). Synthesis and transformation of zero-dimensional Cs3BiX6 (X= Cl, Br) perovskite-analogue nanocrystals. Nano Research, 13, 282-291.
[9] Wang, C., Xiao, J. W., Yan, Z. G., et al. (2023). Colloidal synthesis and phase transformation of all-inorganic bismuth halide perovskite nanoplates. Nano Research, 16(1), 1703-1711.
[10] Zhou, W., Han, P., Zhang, X., et al. (2020). Lead-free small-bandgap Cs2CuSbCl6 double perovskite nanocrystals. The Journal of Physical Chemistry Letters, 11(15), 6463-6467.
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