Research Status of Preparation Technology of Tungsten-based Coatings

Authors

  • Lili Tian

DOI:

https://doi.org/10.62051/ijmee.v8n1.13

Keywords:

Tungsten-based Coatings, Fabrication Processes, Properties, Applications

Abstract

Due to its excellent properties such as high melting point, high hardness, strong corrosion resistance and low saturated vapor pressure, refractory metal W has been widely used in aerospace, nuclear industry, electronics and other fields. However, due to the scarcity and high cost of W resources, its large-scale application in large or complex structural components is severely restricted. In this context, the popularization and use of surface coating technology can not only prepare high-performance W-based coatings on the surface of low-cost substrates, but also solve the cost problem of W resource shortage. At present, the preparation technology of W-based coatings has formed a diversified pattern. Physical vapor deposition, chemical vapor deposition, spraying technology, laser cladding technology and electroplating and other methods each have unique advantages and applicable scenarios. This article will systematically sort out the preparation technology, performance optimization strategies and application status of tungsten-based coatings, analyze the existing problems in current research, and look forward to its future development direction.

References

[1] Guan M. Heat treatment and dynamic mechanical properties of tungsten-based high density alloys[D]. Guangzhou: South China University of Technology, 2018.

[2] Liu Y H, ZHANG Y C, Ge C C. Research progress on preparation technology of metallic tungsten coatings[J]. Materials Science and Engineering of Powder Metallurgy, 2011, 16(3): 315-322.

[3] Cambe A., Gauthier E., Layet J. M., et al. Development of tungsten coating for fusion applications. Fusion engineering and design,2001, 56: 331-336.

[4] Chen Z., Lian Y. Y., Liu X., et al. Recent research and development of thick CVD tungsten coatings for fusion application[J]. Tungsten, 2020, 2(1): 83-93.

[5] Gogova D. S. Optical and structural characterization of tungsten-based CVD metal oxide coatings[J].Materials Letters, 1997, 30(1): 109-113.

[6] Kitaura R, Miyata Y, Xiang R, et al. Chemical vapor deposition growth of graphene and related materials[J]. Journal of the Physical Society of Japan, 2015, 84(12): 121013.

[7] Shao X Q, Yong K Z, Yi B D, et al. Microstructure and mechanical properties of nickel-based coatings fabricated through laser additive manufacturing[J]. Metals, 2021, 11(1): 53.

[8] Figuet D., Billard A., Savall C., et al. A comparison between the microstructure and the functional properties of NiW coatings produced by magnetron sputtering and electrodeposition[J]. Materials Chemistry and Physics, 2022, 276: 125332.

[9] Hoche H, Groß S, Troßmann T, et al. PVD coating and substrate pretreatment concepts for magnesium alloys by multinary coatings based on Ti(X)N[J]. Surface and Coatings Technology, 2013, 228: S336-S341.

[10] Vorobyova M., Biffoli F., Giurlani W., et al. PVD for decorative applications: a review[J]. Materials, 2023, 4919.

[11] Piotrowski O, Madore C, Landolt D. Electropolishing of titanium and titanium alloys in perchlorate-free electrolytes[J]. Plating and Surface Finishing, 1998, 85: 115-119.

[12] Musil J. Recent advances in magnetron sputtering technology[J]. Surface and Coatings Technology, 1998, 100: 280-286.

[13] Schiller S., Goedicke K., Reschke J., et al. Pulsed magnetron sputter technology[J]. Surface and Coatings Technology, 1993,61(1-3): 331-337.

[14] Ning Z D, Wang Y Q, Chen T T, et al. Research progress on magnetron sputtering deposition of silver thin films/coatings[J]. Rare Metal Materials and Engineering, 2022, 51(12): 4773-4782.

[15] Xu Y. F. Preparation of tungsten-based coatings by magnetron sputtering and their damage behavior under deuterium-helium plasma irradiation[D]. Hefei: Hefei University of Technology, 2023.

[16] Guo Z Z, Sun Y, Zhou C, et al. Effect of tungsten content on structure and properties of magnetron sputtered Cu-W alloy films[J]. Materials for Mechanical Engineering, 2011, 35(4): 20-24.

[17] Lagarde M., Billard A., Creus J., et al. Electrochemical behavior of NiW alloys obtained by magnetron sputtering[J]. Surface and Coatings Technology, 2018, (352): 581-590.

[18] Li Z. H., Li J. L., Wang Y. X., et al. Structure of WC coatings prepared by magnetron sputtering and their tribological behavior in water environment[J]. Journal of Natural Science of Harbin Normal University, 2016, 32(2): 94-97.

[19] Zhang Y. C. Lecture 22: Chemical vapor deposition (CVD) technology[J]. Vacuum, 2023, 60(1): 86-88.

[20] Zhang F. L., Wang X., Song K. Q., et al. Research status and progress of tungsten coatings prepared by chemical vapor deposition[J]. Surface Technology, 2020, 49(9): 141-148.

[21] Haygarth John C. Chemical vapor deposition and solar thermal energy conversion[J]. Thin Solid Films, 1980,72(1): 51-58.

[22] Zhang Z. L., Li Z. S., He Q. B., et al. Research on tungsten coatings prepared by chemical vapor deposition and their anti-ablation properties[J]. Surface Technology, 2005, (4): 43-44.

[23] Du J. H., Li Z. X., Gao G. R. Research on tungsten functional coatings deposited by chemical vapor deposition on molybdenum substrate[J]. Rare Metal Materials and Engineering, 2005, (12): 2013-2016.

[24] Zhang H. C. Research on phase composition, microstructure and growth mechanism of CVD tungsten carbide coatings[D]. Beijing: Beijing Institute of Technology, 2018.

[25] Zhang D. H., Qin S. G., Liu G. H. Preparation and bonding performance of tungsten coating on oxygen-free copper surface[J]. Powder Metallurgy Industry, 2019, 29(2): 21-23.

[26] Legg K. O., Graham M., Chang P., et al. The replacement of electroplating[J]. Surface and Coatings Technology, 1996, 81(1): 99-105.

[27] Kamar M T., Elattar H., Mahmoud A. S., et al. A critical review of state-of-the-art technologies for electroplating wastewater treatment[J]. International Journal of Environmental Analytical Chemistry, 2024, 104(16): 4143-4176.

[28] Wang S. H., Zhang H. P., Du H., et al. Development and application of metal electrodeposition technology[J]. Applied Chemical Industry, 2015, 44(4): 732-735.

[29] Gu X. T., Fan P. P., Chen X. C., et al. Preparation and hydrogen evolution performance of nano-porous NiO-Ni/Al3Ni2 composite catalysts[J]. Journal of Functional Materials, 2024, 55(12): 12137-12143.

[30] Gao Q., Bai X., Mou Y., et al. Effect of tungsten content on tribological properties of Ni-W alloy coatings[J]. Lubrication Engineering, 2024, 49(9): 135-141+190.

[31] Liu S. Research on electrodeposition process of nickel-tungsten alloy[D]. Harbin: Harbin Institute of Technology, 2016.

[32] Figuet D., Billard A., Savall C., et al. A comparison between the microstructure and the functional properties of NiW coatings produced by magnetron sputtering and electrodeposition[J]. Materials Chemistry and Physics, 2022, 276: 125332.

[33] Druga J, Kašiarová M, Dobročka E, et al. Corrosion and tribological properties of nanocrystalline pulse electrodeposited Ni-W alloy coatings[J]. Transactions of the IMF, 2017, 95(1): 39-45.

[34] Sunwang N., Panyawat W. Y., Yuttanant B. The effects of heat treatments on hardness and wear resistance in Ni–W alloy coatings[J]. Surface and Coatings Technology, 2011,206(6): 1096-1101.

[35] Lima-Neto P. D, Correia A. N., et al. Morphological, structural, microhardness and electrochemical characterisations of electrodeposited Cr and Ni–W coatings[J]. Electrochimica Acta,2010,55(6): 2078-2086.

[36] Wu B., Xu B. S, Zhang B, et al. The effects of parameters on the mechanical properties of Ni-based coatings prepared by automatic brush plating technology[J]. Surface and Coatings Technology,2007,201(12): 5758-5765.

[37] Krella A. K., Grzes J., Erbe A., et al. Behaviour of nickel coatings made by brush plating technology in conditions of cavitation erosion and corrosion[J]. Wear,2023,530: 204998.

[38] Jie X. H., Chen Y. D., Xie G. R., et al. High-temperature oxidation and wear characteristics of Ni-W alloy brush plating coatings[J]. The Chinese Journal of Nonferrous Metals, 2003(4): 979-983.

[39] Zhu L, Younes O, Ashkenasy N, et al. STM/AFM studies of the evolution of morphology of electroplated Ni/W alloys[J]. Applied Surface Science, 2002, 200(14): 1-14.

[40] Ding L H, Lei W N, Tang C S, et al. Study on nickel-tungsten alloy brush plating coating for crankshaft[J]. Electroplating & Pollution Control, 2015, 25(5): 19-22.

[41] Chen Y D. Repair of adhesive wear of forming molds by brush plating with In and Ni-W(D) composite coatings[J]. New Technology & New Process, 2016(3): 84-87.

[42] Hu Y H, Yu Y D, Ge H L, et al. Study on mechanical and anticorrosion performance of NiW alloy coatings prepared by induced codeposition[J]. International Journal of Electrochemical Science,2019,14(2): 1649-1657.

[43] Hu, S. B., Tu J. P., Mei Z., et al. Adhesion strength and high temperature wear behaviour of ion plating TiN composite coating with electric brush plating NiW interlayer[J]. Surface and Coatings Technology,2001,141.2-3: 174-181.

[44] Ding R, Wang X H, Hu C H, et al. Research status of material systems for laser cladding technology[J]. Hot Working Technology, 2025, 54(20): 1-9.

[45] Zhong M L, Liu W. Proceedings of the Institution of Mechanical Engineers, Part C: Journal of Mechanical Engineering Science[J], 2010, 224(5): 1041.

[46] Yang L, Yu T B, Li M, et al. Ceramics International[J], 2018, 44(18): 22538.

[47] Saeedi R, Razavi R S, Bakhshi S R et al. Ceramics Internat- ional[J], 2021, 47(3): 4097.

[48] Shan S S, Ge Y Y, Zhong Q S, et al. Microstructure and properties of WC-reinforced FeCoNiCrAl high-entropy alloy composite coatings prepared by laser cladding[J]. Transactions of Materials and Heat Treatment, 2025, 46(8): 187-198.

[49] Fu S, Xu A J, Xu Y X, et al. Preparation and friction and wear properties of WC gradient wear-resistant coatings prepared by laser cladding[J]. Journal of Materials Protection, 2025, 58(4): 40-47.

[50] Wu X W, Zeng X Y, Zhu B D, et al. Study on cracking behavior of Ni-based WC metal-ceramic laser cladding layers[J]. Chinese Journal of Lasers, 1997(6): 91-97.

[51] Herman, Herbert, Sanjay Sampath, et al. Thermal spray: current status and future trends[J]. MRS bulletin, 2000,25(7): 17-25.

[52] Fauchais, Pierre L., Joachim VR Heberlein, et al. Industrial applications of thermal spraying technology. Thermal spray fundamentals: from powder to part. Boston, MA: Springer US, 2013, 1401-1566.

[53] Jian Z H, Ma Z, Wang F C, et al. Research on process properties of thermally sprayed copper-based W coatings[J]. Ordnance Material Science and Engineering, 2007(2): 27-30.

[54] Ma W Y, Liu M, Zhou K S, et al. Structure and properties of laser remelted tungsten plasma sprayed coatings on copper substrate[J]. Journal of Materials Protection, 2010, 43(6): 65-67+93.

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Published

20-01-2026

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Articles

How to Cite

Tian, L. (2026). Research Status of Preparation Technology of Tungsten-based Coatings. International Journal of Mechanical and Electrical Engineering, 8(1), 110-119. https://doi.org/10.62051/ijmee.v8n1.13